|
Catalyst |
Reaction |
|
Metals (e.g., Ni, Pd, Pt, as powders
Or on supports) or metal oxides (e.g., Cu,
Ni, Pt) |
C= C bond hydrogenation, e.g.,
olefin
+ H2
→ parafin |
|
Metals (e.g., Cu, Ni, Pt)
|
C= O
bond hydrogenation, e.g.,
acetone+H2
→ isopropanol |
|
Metal (e.g., Pd, Pt) |
Complete oxidation of
Hydrocarbons,
Oxidation of CO |
|
Fe
(supported and promoted with Alkali metals)
|
3
H2 + N2 →
2 NH3 |
|
Ni |
CO
+ 3 H2 →
CH4 + H2O |
|
Fe or
Co (supported and promoted With alkali metals) |
CO+H2 → parafins + olefins +H2O + CO2
(+ other oxygen-containing compounds) |
|
Cu
(supported on ZnO, with other Components e.g., Ai2O3) |
CO + 2H2
→
CH3OH |
|
Re + Pt
(supported on a-Al2O3 or b-Al2O3
promoted with chloride) |
Paraffin dehydrogenation,isomerization and
dehydrocyclization |
|
Solid
acids (e.g., SiO2, Al2O3,
zeolites) |
Parafin cracking and isomerization |
|
b-Al2O3
|
Alcohol
→
olefin + H2O |
|
Metal-oxide supported complexes of Cr, Ti or Zr |
Olefin polymerization, e.g.,
ethylene
→ polyethylene |
|
Pd
supported on acidic zeolite |
Paraffin hydrocracking |
|
Metal-oxide supported complexes of W or Re |
Olefin metathesis, e.g.,
propylene
→
ethylene + butane |
|
Ag (on
inert supported, promoted by Alkali metals) |
Ethylene
+ 1/2O2
→
ethylene Oxide (with CO2 + H2O) |
|
V2O5
or Pt |
2SO2
+ O2
→
2 SO3 |
|
( V2O5
(on metal oxide support |
Naphtalene + 9/2 O2
→
Phthalic anhydride + 2CO2 + 2H2O |
|
Bismuth
molybdate |
Propylene
+ 1/2 O2
→
acrolein |
|
Mixed
oxides of Fe and Mo |
CH3OH
+ O2
→
formaldehyde
(with CO2 + H2O) |
|
Fe3O4
or metal sulfides |
H2O
+ CO
→
H2 + CO2 |